Resumen ejecutivo
Sedimentation is recommended as simple pre-treatment of water prior to application of other purification treatments such as filtration and disinfection methods. It removes undesirable small particulate suspended matters (sand, silt and clay) and some biological contaminants from water under the influence of gravity. The longer the water is sedimented, the more the suspended solids and pathogens will settle to the bottom of the container. Adding special chemicals or some natural coagulants can accelerate sedimentation. Three common chemicals used are aluminium sulphate, polyaluminium chloride (also known as PAC or liquid alum) and ferric sulphate. 'PUR' is a powder product containing both coagulants and disinfectant. Some native plants like prickly pear cactus, Moringa seeds, broad beans and Fava beans have all been traditionally used as natural coagulant to help sediment water in a number of countries in Africa and Latin America.
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Drinking Water |
Introduction
The suspended particles in water vary considerably in source, composition, charge, particle size, shape and density. The smaller particles present in water are kept in suspension by the action of physical forces on the particles themselves. One of the forces playing a dominant role in stabilisation results from the surface charge present on the particles. Most solids suspended in water possess a negative charge and since they have the same charge sign, repel each other when they come close together. Therefore they will remain in suspension rather than clump together and settle out of the water.
Sedimentation is a simple, low cost pre-treatment technology to reduce settable solids and some microbes from water under the influence of gravity prior to application of other purification methods. It also improves the visual qualities of the water and increases its acceptance by consumers. The longer the water is stored, the more the suspended solids and pathogens will settle to the bottom of the container. Adding chemical or natural coagulants to the water can quicken the sedimentation process. Aluminium sulphate, polyaluminium chloride (also known as PAC or liquid alum) and ferric sulphate are three common types of chemicals used for the coagulation. Some examples of natural coagulants are prickly pear cactus, Moringa seeds, broad beans and Fava beans. Some products like “PUR” contain both coagulants and disinfectant. Coagulants are dosed in solution at a rate determined by raw water quality. After sedimentation, the water should be filtered to further remove suspended materials and pathogens.
Working mechanism
Much of the suspended material can be removed by simply allowing the water to stand and settle for some time. This retention time (from one hour up to two days, the longer the better) is required to settle particles in the bottom. Storing water for at least one day will also promote the natural die-off of some bacteria.
Coagulants enhance sedimentation because they neutralise the surface charge of suspended particles. Particles that cause turbidity (e.g. silt, clay) are generally negatively charged, making it difficult for them to clump together because of electrostatic repulsion. But chemical coagulant particles are positively charged, and they chemically attracted to negative turbidity particles, neutralising the latter’s negative charge and accumulate to form larger particles (flocs), which settle faster.
Natural coagulants contain significant quantities of water-soluble proteins, which carry an overall positive charge when in solution. The proteins bind to the predominantly negatively charged particles that cause turbidity and form flocs. The flocs can be settled out or removed by filtration. Bacteria and viruses can attach themselves to the suspended particles in water. Therefore, reducing turbidity levels through coagulation may also improve the microbiological quality of water.
Effectiveness
Plain sedimentation often is effective in reducing water turbidity, but it is not consistently effective in reducing microbial contamination. Storing water for as little as a few hours will sediment the large, dense particles like inorganic sands and silts, large microbes and any other. Overnight or 1-2 days longer settling times will remove larger microbes, including Helminth ova and some parasites, some microbes, such as certain algae, and the larger clay particles. Most viruses and bacteria and fine clay particles are too small to be settled out by simple gravity sedimentation.
Sedimentation by using coagulant reduces the time required to settle out suspended solids and is very effective in removing fine particles. Some bacteria and viruses can also attach themselves to suspended particles. Therefore, reducing turbidity level through coagulation may also improve some microbiological quality (bacteria, viruses, protozoa and helminths) of water (AMAGLOH& BENANG 2009).
The use of Moringa Oleifera seeds for water treatment is efficient in reducing 80% to 99.5% of turbidity accompanied by 90% to 99.99% bacterial reduction (LEA 2010).
| Viruses | Helminths | |||
Laboratory | >90 to >99%1 | >90 to >99%1 | >90 to >99%1 | >90 to >99%1 | 80-99.5%2 |
Field | < 90%3 |
|
|
| 95%2 |
Summary of Treatment efficiency of sedimentation with the aid of natural & chemical coagulants. Adapted from CAWST (2009)
The effectiveness of the coagulants has a complex dependence on the type of coagulant used, the nature of the raw water, being affected by such things as temperature, pH and especially the specific proportions of organic, inorganic and biological particles that constitute the suspended solids as well as mixing. The best approach for determining the treatability of a water source and determining the optimum parameters (most effective coagulant, required dose rates, pH) is by use of a jar tester. Plain sedimentation or settling is not effective for removing dissolved chemicals from the water.
Sedimentation is used to remove solids from water. It is suitable for water with high sediment content. It is easy to perform and requires a minimum of materials and skill. It can be done with as little as two or more simple storage vessels such as pots and buckets by manual transfer. Typically, at least two containers are needed to settle water: one to act as the settling vessel and another to be the recipient of the supernatant water after the settling period. Care must be taken to avoid disturbing the sedimented particles when recovering the supernatant water by decanting or other methods. Staffs need to be adequately trained to carry out jar tests to determine coagulant dosage. For better results, the coagulants should be rapidly and thoroughly mixed in water. Coagulants can be expensive to buy (particularly polyelectrolyte) and need accurate dosing equipment to function efficiently.
When water is sedimented in vessel, the sediment should be removed and the vessel should be cleaned after each use. More rigorous physical or chemical cleaning is needed to avoid the microbial colonization of the vessel surface.
Some communities have opted not to use aluminium based coagulants because of unsubstantiated reports that claim that the aluminium in drinking water poses a risk to public health despite of scientific evidences (SRINIVASAN et al. 1999). Based on the WHO (2008), there is no evidence of health risk.Studies have been carried out to determine the potential risks associated with the use of M. Oleifera seed in water treatment but there is no evidence to suggest any acute or chronic effects on humans, particularly at the low doses required for water treatment (FOLKARD et al. 1998).
Effectiveness of Moringa Oleifera Seed as Coagulant for Water Purification
A research carried out to examine the effectiveness of powder extracted from mature dried Moringa oleifera seeds as a coagulant, which is commonly available in most rural communities of Africa. The results obtained showed that powder from seed kernels of Moringa Oleifera contains coagulating properties at loading doses of 10 g/L and above that have similar effect as the conventional coagulant, alum.
AMAGLOH, F.K. ; BENANG, A. (2009): Effectiveness of Moringa Oleifera Seed as Coagulant for Water Purification. URL [Visita: 21.05.2019]Treating the Public Water Supply: What Is In Your Water, and How Is It Made Safe to Drink?
Chemical Coagulants
A three-page factsheet containing information on treatment efficiency, operating criteria and other relevant information on chemical coagulants.
CAWST (2009): Chemical Coagulants. (= Household Water Treatment and Safe Storage Fact Sheets ). Calgary: Centre for Affordable Water and Sanitation Technology (CAWST) URL [Visita: 21.05.2019]A simple way to clean water
Water Clarification using Moringa Oleifera Seed Coagulant
This technical brief gives an overview of the application of an indigenous, naturally derived coagulant, namely seed material from the multi-purpose tree Moringa Oleifera, which offers an alternative solution to the use of expensive chemical coagulants.
FOLKARD, G. SUTHERLAND, J. SHAW, R. (1998): Water Clarification using Moringa Oleifera Seed Coagulant. Loughborough (U.K.): Water and Environmental Health at London and Loughborough (WELL), Loughborough University, Technical Brief 60, pp.109-112 URL [Visita: 21.05.2019]Bioremediation of Turbid Surface Water Using Seed Extract from Moringa Oleifera Lam. (Drumstick) Tree
Lesson 9: Colloids and Coagulation
Aluminium in Drinking Water: an Overview
Guidelines for Drinking-water Quality, Third Edition
This volume of the Guidelines for Drinking-water Quality explains requirements to ensure drinking-water safety, including minimum procedures and specific guideline values, and how those requirements are intended to be used. The volume also describes the approaches used in deriving the guidelines, including guideline values. It includes fact sheets on significant microbial and chemical hazards.
WHO (2008): Guidelines for Drinking-water Quality, Third Edition. Third Edition incorporating the First and Second Addenda. Geneva: World Health Organization (WHO) URL [Visita: 23.04.2012]Review of Coagulation Technology for Removal of Arsenic: Case of Chile
This paper presents a summary of the process, concepts and operational considerations for the use of coagulation technology for removal of arsenic in Chile.
SANCHA, A. M. (2006): Review of Coagulation Technology for Removal of Arsenic: Case of Chile. Entradas: Journal of Health, Population and Nutrition: Volume 24 , 267-272. URL [Visita: 14.05.2012]Chemical Coagulants
A three-page factsheet containing information on treatment efficiency, operating criteria and other relevant information on chemical coagulants.
CAWST (2009): Chemical Coagulants. (= Household Water Treatment and Safe Storage Fact Sheets ). Calgary: Centre for Affordable Water and Sanitation Technology (CAWST) URL [Visita: 21.05.2019]PUR
A four-page factsheet containing product information on the procedure of using PUR flocculant and disinfectant powder, its treatment efficiency, operating criteria and other relevant information’s related to PUR.
CAWST (2009): PUR. Calgary: Centre for Affordable Water and Sanitation Technology (CAWST). Household Water Treatment and Safe Storage Fact Sheets URL [Visita: 24.05.2019]Natural Coagulants
A four-page factsheet containing information on treatment efficiency, operating criteria and other relevant information related to natural coagulants.
CAWST (2009): Natural Coagulants. (= Household Water Treatment and Safe Storage Fact Sheets ). Calgary: Centre for Affordable Water and Sanitation Technology (CAWST) URL [Visita: 21.05.2019]Settling
A three-page factsheet containing introduction, operation procedure, treatment efficiency, operating criteria and other information related to settling.
CAWST (2009): Settling. (= Household Water Treatment and Safe Storage Fact Sheets ). Calgary: Centre for Affordable Water and Sanitation Technology (CAWST) URL [Visita: 21.05.2019]Flocculant/Disinfectant Powder
A two-page factsheet on PUR flocculant and disinfectant powder with field and lab, containing information on effectiveness, advantages and limitations and implementation examples.
CDC ; USAID (2008): Flocculant/Disinfectant Powder . (= CDC Household Water Treatment Options in Developing Countries Factsheets ). New York: Center for Disease Control and Prevention (CDC) and United States Agency for International Development (USAID) URL [Visita: 24.05.2019]Water Clarification using Moringa Oleifera Seed Coagulant
This technical brief gives an overview of the application of an indigenous, naturally derived coagulant, namely seed material from the multi-purpose tree Moringa Oleifera, which offers an alternative solution to the use of expensive chemical coagulants.
FOLKARD, G. SUTHERLAND, J. SHAW, R. (1998): Water Clarification using Moringa Oleifera Seed Coagulant. Loughborough (U.K.): Water and Environmental Health at London and Loughborough (WELL), Loughborough University, Technical Brief 60, pp.109-112 URL [Visita: 21.05.2019]Arsenic Removal from Drinking Water During Coagulation
This paper presents the findings of a study on the efficiency of arsenic removal from source water and artificial freshwater during coagulation with ferric chloride and alum. They found that pH range for arsenic (V) removal with alum was more restricted than with ferric chloride and that arsenic (III) could not be removed from source water by coagulation with alum.
HERING, J.G. ; PEN-YUAN, C. ; WILKIE, J.A. ; ELIMELECH, M. (1997): Arsenic Removal from Drinking Water During Coagulation. Entradas: Journal of Environmental Engineering: Volume 123 , 800-807. URL [Visita: 14.05.2012]Smart Disinfection Solutions
This booklet, part of the Smart Water Solutions series provides a wide range of methods and products for home water treatment in rural areas.
NWP (2010): Smart Disinfection Solutions. Examples of small-scale disinfection products for safe drinking water. (= Smart water solutions ). Amsterdam: KIT Publishers URL [Visita: 17.05.2019]Household Treatment and Storage
This technical brief presents the current options for safe storage and overview of seven types of point of use water treatment options. It also explains the working mechanism, and discusses the microbiological effectiveness of ceramic candle filter as well as community acceptance and sustainability.
OXFAM (2008): Household Treatment and Storage . (= Technical Brief No. 4 ). Oxford: OXFAM URL [Visita: 20.05.2019]Improving Filtrate Quality Using Agro based Materials as Coagulant Aid
This research assesses the agro based materials like Surjana seed (Moringa oleifera), Nirmali seed (Strychnos pototorum) and maize (Zeemays) as a coagulant aid in conjunction with alum to determine their efficacy in water treatment. Experiments have been conducted simulating a conventional water treatment train consisting of coagulation-flocculation-settling and granular media filtration. They found that filtrate quality has improved with the use of agro-based materials.
RAGHUWANSHI, P.K. ; MANDLOI, M. ; SHARMA, A.J. ; MALVIYA, H.S. ; CHAUDARI, S. (2002): Improving Filtrate Quality Using Agro based Materials as Coagulant Aid. Entradas: Water Quality Research Journal of Canada: Volume 37 , 745-756. URL [Visita: 24.05.2019] PDFWater Clarification Using Moringa oleifera
Technical information on water clarification using Moringa Oleifera, with preparation techniques of the coagulant solution, method of treatment, dosage, advantage and disadvantages of the natural coagulant with useful links.
SCHWARZ, D. (2000): Water Clarification Using Moringa oleifera. Eschborn: GATE-GTZ URL [Visita: 21.05.2019]Promotion of household water treatment and safe storage in UNICEF WASH programmes
Short introduction to household water treatment and the main treatment methods.
UNICEF (2008): Promotion of household water treatment and safe storage in UNICEF WASH programmes. pdf presentation. New York: United Nations Children's Fund URL [Visita: 17.03.2010]Application of Indigenous Materials in Drinking Water Treatment
In this study, volcanic ash and Moringa oleifera (M. oleifera) were investigated as indigenous materials for drinking water treatment based on problems identified at Kampala and Masaka water treatment plants in Uganda.
KALIBBALA, H.M. (2007): Application of Indigenous Materials in Drinking Water Treatment. Stockholm: Royal Institute of Technology (KTH) URL [Visita: 24.05.2019]Conservation et Traitement de l Eau a Domicile
This practical guide provides a review of different processing techniques and adequate water conservation at home and is structured around 10 key questions that should be posed before choosing a suitable solution.
DESILLE, D. (2013): Conservation et Traitement de l Eau a Domicile. Paris: Programme Solidarite Eau (PSeau) URL [Visita: 06.06.2013]Application of the Purified Moringa Oleifera Coagulant for Surface Water Treatment
This study investigated the effectiveness of the Moringa oleifera coagulant for the removal of turbidity, bacteria, and natural organic matter (NOM) from natural surface water. The results obtained were compared with inorganic coagulants of alum and ferric chloride.
ABALIWANO, J.K. GHEBREMICHAEL, K.A. AMY, G.L. (2008): Application of the Purified Moringa Oleifera Coagulant for Surface Water Treatment. Watermill Working Paper Series No. 5). Delft: United Nations Educational, Scientific and Cultural Organization, Institute for Water Education (UNESCO-IHE) URL [Visita: 24.05.2019]Effectiveness of Moringa Oleifera Seed as Coagulant for Water Purification
A research carried out to examine the effectiveness of powder extracted from mature dried Moringa oleifera seeds as a coagulant, which is commonly available in most rural communities of Africa. The results obtained showed that powder from seed kernels of Moringa Oleifera contains coagulating properties at loading doses of 10 g/L and above that have similar effect as the conventional coagulant, alum.
AMAGLOH, F.K. ; BENANG, A. (2009): Effectiveness of Moringa Oleifera Seed as Coagulant for Water Purification. URL [Visita: 21.05.2019]Home Water Treatment by Direct Filtration with Natural Coagulant
This study examines the quality improvement of surface water by direct filtration with Strychnos Potatorum seed or Moringa Oleifera seed as the coagulant and assesses the suitability for home water treatment in rural areas of developing countries.
BABU, R. ; CHAUDHURI, M. (2005): Home Water Treatment by Direct Filtration with Natural Coagulant. Entradas: Journal of Water and Health: Volume 3 , 27-30. URL [Visita: 24.05.2019]Point-of-use Water Treatment and Diarrhoea Reduction in the Emergency Context: an Effectiveness Trial in Liberia
This paper includes findings of a twelve-week effectiveness study of point of use water treatment with flocculant-disinfectant among 400 households in camps for displaced populations in Monrovia, Liberia.
DOOCY, S. ; BURNHAM, G. (2006): Point-of-use Water Treatment and Diarrhoea Reduction in the Emergency Context: an Effectiveness Trial in Liberia. Entradas: Tropical Medicine and International Health: Volume 11 , 1542-1552. URL [Visita: 24.05.2019]Moringa Seed and Pumice as an Alternative Natural Material for Drinking Water Treatment
This research thesis presents an investigation on the suitability of pumice and seeds of Moringa Oleifera as natural materials for drinking water treatment based on the problem identified on the Stretta Vaudetto water treatment plant in Eritrea.
GHEBREMICHAEL, K.A. (2004): Moringa Seed and Pumice as an Alternative Natural Material for Drinking Water Treatment. (= Doctoral Thesis ). Stockholm: Royal Institute of Technology (KTH) URL [Visita: 24.05.2019]Toward Understanding the Efficacy and Mechanism of Opuntia spp. As a Natural Coagulant for Potential Application in Water Treatment
In this study, the coagulant properties of Opuntia spp., a species of cactus, are quantitatively evaluated.
MILLER, S.M. ; FUGATE, E.J. ; CRAVER, V.O. ; SMITH, J.A. ; ZIMMERMAN, J.B. (2008): Toward Understanding the Efficacy and Mechanism of Opuntia spp. As a Natural Coagulant for Potential Application in Water Treatment. Entradas: Environmental Science & Technology: Volume 42 , 4274–4279. URL [Visita: 24.05.2019]Moringa as an Alternative to Aluminium Sulphate
This paper discusses different features of Moringa oleifera seed and assesses it as a potential alternative to aluminium sulphate for water treatment in rural and urban areas. Paper presented on 27th WEDC Conference in Lusaka, Zambia.
NKHATA, D. (2001): Moringa as an Alternative to Aluminium Sulphate. Entradas: People and Systems for Water, Sanitation and Health. Papers of the 27th WEDC Conferences, Zambia: , 236-238. URL [Visita: 21.05.2019]Review of Coagulation Technology for Removal of Arsenic: Case of Chile
This paper presents a summary of the process, concepts and operational considerations for the use of coagulation technology for removal of arsenic in Chile.
SANCHA, A. M. (2006): Review of Coagulation Technology for Removal of Arsenic: Case of Chile. Entradas: Journal of Health, Population and Nutrition: Volume 24 , 267-272. URL [Visita: 14.05.2012]Moringa: eine mögliche Hochpreiskultur für Industrie und Landwirtschaft in weniger entwickelten Ländern
A PDF presentation with an overview on the Moringa plant. It includes general information, its different uses, methods of cultivation and other relevant topics on the Moringa plant (in German).
BECKER, K. (n.y): Moringa: eine mögliche Hochpreiskultur für Industrie und Landwirtschaft in weniger entwickelten Ländern.Household Water Treatment Manual
This manual on household water treatment system includes various useful topics on safe water and multi barrier approach (source protection, sedimentation, filtration, disinfection and safe storage).
CAWST (2008): Household Water Treatment Manual. Calgary: Centre for Affordable Water and Sanitation Technology (CAWST)An Introduction to Household Water Treatment and Safe Storage, A CAWST Training Manual
This training manual describes the need of safe drinking water and sanitation and provides relevant information on HWTS process, technologies. It is good reference material for trainers to conduct training on HWTS.
CAWST (2009): An Introduction to Household Water Treatment and Safe Storage, A CAWST Training Manual. Calgary: Centre for Affordable Water and Sanitation Technology (CAWST) URL [Visita: 13.05.2019]Evaluating Coagulant for Water Treatment. Presentation
This document is an overview presentation on different coagulants, discussing different case studies with field results and some lessons learned. Presented in PNWS-AWWA Section Conference.
DUNCAN, K. WISE, D. (2008): Evaluating Coagulant for Water Treatment. Presentation. American Water Works Association, Pacific Northwest Section (PNWS-AWWA) URL [Visita: 21.05.2019]Household water treatment and safe storage in emergencies
This document is intended as a general manual on household water treatment and storage in emergencies. Methods of treatment but also promotion are presented, including factsheets, a decision tree and very comprehensive illustrations.
IFRC (2008): Household water treatment and safe storage in emergencies. pdf presentation. Geneva: International Federation of Red Cross and Red Crescent Societies (IFRC) URL [Visita: 23.04.2012]The Three-Pot Water Treatment System
This poster is part of the series of Water, Sanitation and Hygiene posters designed by the Water, Engineering and Development Center of Loughborough University.
SKINNER, B.H. SHAW, R. (2013): The Three-Pot Water Treatment System. Poster. (= WEDC Posters, 002 ). London: Water, Engineering and Development Center (WEDC) URL [Visita: 28.08.2013]Colloids and Coagulation
This weblink gives information on properties of colloids, their relationship with coagulation and effects of zeta potential on coagulation.